Beyond Lithium-Ion

Today's Li-ion battery technology has changed the way we live. This amazing energy storage device has allowed people to run computers that can transmit data to cell towers and run dozens of applications and yet fit in the palms of our hands.It has also enabled the production of vehicles that can travel over 250 miles in a single charge. Unfortunately, the technology for vehicles is still too expensive for mass market penetration, which could be addressed with a step change in energy density. It is for this reason that the Department of Energy(DOE) Vehicle Technology Office (VTO) puts a significant portion of its budget towards what is often referred to as "Beyond Li-ion." Beyond Li-ion envisions the use of lithium metal as the anode in place of graphite. A direct replacement of equivalent capacity would result in a 10-fold reduction in the mass anode active material. To support such an effort,VTO funds several initiatives in battery research, starting with Enabling Li-metal.

DOE Energy Storage Initiatives in Beyond Li-ion

Enabling Li-metal

This initiative focuses on understanding the fundamentals of lithium metal plating and devising ways to prevent dendrite formation and intolerable levels of coulombic inefficiency. Some of the more popular approaches for achieving these goals is the formation of microstructures that allow for the accumulation of lithium without the formation of branches or mossy structures. Also being pursued are solid electrolytes, both organic and inorganic, that physically prevent the growth of dendrites during plating. A thirdl approach is the development of a liquid electrolyte that simultaneously promotes smooth deposition and is nearly completely inert to lithium reduction.

Specific projects at Berkeley Lab (LBNL) include:

Synthesis and Characterization of Polysulfone-based Copolymer Electrolytes

Solid state batteries with long cycle life and high energy density through materials design and integration.
- This is a new multi-investigator project and involves the development of novel buffer layers to eliminate lithium dendrite formation; new, stable, highly-conductive inorganic electrolytes, and methods for fabricating cyclable, all-solid-state, high capacity cathodes, and thin (<20 micron) separators.

Sulfur

Sulfur has a theoretical first charge capacity of over 1675 mAh/g, ten times the capacity for lithium compared to today's lithium-ion cathodes. The problem with sulfur is that it forms soluble lithium-polysulfide components in liquid electrolytes as it is lithiated from sulfur to lithium sulfide. These soluble components can migrate to the anode in the liquid electrolyte resulting in coulombic inefficiency and loss of sulfur. Also, lithium sulfide, which makes up at least 50% of the cells capacity during the last stage of lithiation, is non-soluble and an insulator, both ionic and electronic. Despite these challenges, one immediately sees that the efficiency problem could be eradicated if a suitable solid electrolyte was found for Enabling Li-metal.

Specific Projects at LBNL include:

Simulations and X-ray Spectroscopy of Li-S Chemistry

New Electrolytes for Lithium Sulfur Batteries

Modeling

The recent advent of high performance computing (HPC) has enabled the ability to use computers for amazingly complex problems requiring detailed modeling and thousands of computations. Success in this field, as demonstrated by the Materials Project among other activities, has demonstrated that we can now design new materials with computers and estimate their properties, such as diffusion of ions, voltage for intercalation, and capacity for ions of any size. Researchers have also shown that in a reasonable amount of time, they can calculate the stability of electrolytes and determine the reaction products. This capability is being supported to identify new cathode materials with high voltage, high capacity, and low scarce-metal content and new electrolytes that are compatible with lithium.

Specific projects at LBNL:

Predicting and Understanding Novel Electrode Materials from First-Principles

First Principles Calculations of Existing and Novel Electrode Materials

Design and Synthesis of Advanced High-Energy Cathode Materials

Large-scale ab initio Molecular Dynamics Simulations of Liquid and Solid Electrolyte

Advanced Diagnostics

Many of the challenges to finding better materials is fully understanding why the materials we have do not work on the nano and atomic level. For this reason, DOE continuously supports the development of new techniques; if we can understand what is occurring, we can change it. The national labs are the home to some of the most powerful experimental resources in the world, from synchrotron light sources to supercomputer clusters to powerful microscopes to facilities designated specifically to nano science. Finding new ways to use these instruments to understand electrochemical phenomena from an ex situ, in situ, and in operando basis is core to DOE's mission.

Specific projects at LBNL include:

In-Operando Thermal Diagnostics of Electrochemical Cells

lnterfacial Processes via Near-Field Imaging

Investigating High Voltage Li Cathode-Electrolyte Interfacial Processes

Sodium Ion

A possible bottleneck in the scale development of massive scale deployment of Li-ion batteries could be the limitation of lithium on the planet. After cobalt, lithium is the next most expensive element in the battery on a per gram basis. Replacing lithium will not be easy as it is the third smallest element in the periodic table and intercalates into many materials. However, sodium is just below it in the periodic table and is far more abundant. There have been several cathode materials discovered that will intercalate sodium to nearly the same degree as lithium but not many anodes. Sodium does not intercalate into graphite nearly to the degree that lithium does. To overcome this obstacle, DOE supports efforts in discovering new, high-capacity, low voltage Na-ion anodes. One can easily foresee that the cost of intercalation batteries would drop again if the main ion were sodium and not lithium.