Electrochem Seminar - Impact of Inactive Components and Process Conditions on Electrode Performance

Electrochem Seminar - Impact of Inactive Components and Process Conditions on Electrode Performance

Abstract

Our group carefully examines the impact of processing conditions and formulations on the performance of electrodes.  Our goal is to understand why different mixers and combinations of conductive additives and binders are suggested for nearly every change in cathode or anode active material.  We conduct this work by measuring the physical properties of the individual constituents and try to connect those properties to the electrochemical properties of the final electrode through analyzing the dispersement of the materials, the rheological properties of the slurries, the quality of the dried laminates (lack of cracks), and the mechanical and electrical properties of the dried electrodes.  This year we discovered that the binder does not bind to the current collector without the addition of solids, the maximum solids content is related to the surface area of the solids, there appears to be a magical level of solvent for the slurries that is linearly dependent on the surface area of the carbon that leads to quality laminates, and the carbon additive plays an important physical role in the processing of the electrodes well beyond providing electronic conductivity. Simply put, there is a lot more to the binder and carbon than holding the particles together and enhancing the electronic conductivity.

Speaker

Vincent Battaglia

Vince Battaglia is a Research Scientist and Group Leader of The Battery Group.  A chemical engineer by training, Vince has been studying electrode formulations and processing conditions for high loading electrodes since arriving at Berkeley in 2004.  His group is presently involved in improving the performance of the electrodes of several materials including DRX, NMC, Si, several solid-state chemistries, and the active buffer layer being considered for lithium dendrite prevention. He has over 135 publications and holds 10 patents.

Summary notes

Vince Battaglia 05/09 Seminar Slide showing graphs of Technical Accomplishments and Progress of CB:B Ratio

Date/Time
Monday, May 9, 2022 - 03:00pm to 03:30pm
PI
Vince Battaglia